Search Results

24.05.12 - MDI handbook 2019 - BASF.pdf

Diphenylmethane diisocyanate (MDI) is a member of the diisocyanate family associated with polyurethane chemistry. The term polyurethane applies to a large number of polymers formed through the polyaddition of polyfunctional isocyanates and isocyanate-reactive ...

MDI Production Process In the MDI process, aniline is condensed with formaldehyde to produce methylenedianiline (MDA), and MDA is reacted with phosgene to form MDI. The flexibility of the BASF process makes it possible to control and modify the properties of ...

Acute Hazards MDI and products containing unreacted MDI are potentially hazardous materials. Therefore, a thorough knowledge of potential dangers, with strict adherence to recommended safety practices, is essential before MDI products are handled, stored, or ...

MDI and products containing MDI are reactive and potentially hazardous chemicals. MDI should only be handled by knowledgeable and well-trained personnel who thoroughly understand the hazards associated with the transportation, storage, and use of the chemical....

Although MDI is a hazardous material in terms of reactivity and toxicity, it can be transported and handled safely provided that appropriate precautions are observed. Regulations The shipment of MDI and MDI-containing products are subject to strict regulatio...

Storage and Handling Considerations A thorough knowledge of the chemical and physical properties of MDI, as well as all federal and local regulations and building codes, is necessary for the safe handling and storage of MDI products. When designing storage s...

Guidelines for Dealing with MDI Product Incidents All incidents are unique so it is not possible to write guidelines to deal with every circumstance. Each incident must be assessed from the information available. All people involved with the handling or tran...

The following recommendations should be interpreted in light of existing and future legislation. The disposal of liquid MDI wastes and used containers may be regulated by local, state, provincial, and federal agencies. Disposal of Waste MDI Products MDI prod...

1. What are the standards for unloading bulk MDI from truck or rail? The operation of unloading (or loading) any tank truck, iso tank container, tank car, or small container of MDI is potentially hazardous. Unloading facilities must be designed and located gi...

Equipment Guidelines for Diisocyanate Storage Tanks This Technical Bulletin is intended to provide guidelines for describing various equipment options for storagetank systems intended for diisocyanate product service. The bulletin includes a reference table o...

24.05.12 - Guidelines for Isocyante Storage Tanks.pdf

Product MMDI PMDI TDI 1. Impervious Spill Containment T T T 2. Material of Construction Unlined Carbon Steel S T T Lined Carbon Steel S S S Stainless Steel S S S 3. Tanks: General Above ...

1. Impervious Spill Containment Capacity and construction details of the containment area for a storage tank vary according to state and local building codes, but, generally, tanks are installed in areas intended to provide an impervious surface and a defined...

This guidance document is designed specifically for medical personnel to provide current information about the potentialhealth effects from diisocyanate (1) exposure, and to provide guidance to assist with medical diagnosis and management. The discussion focus...

RESPIRATORY EFFECTS The predominant health effect of MDI and TDI is on the respiratory tract. Both chemicals have been shown to be portal-of-entry toxicants. INHALATION OF VAPORS AND MISTS MDI: At room temperature, MDI has a relatively low vapor pressure i...

EXPOSURE GUIDELINES Irritation and sensitization are the primary hazards associated with dermal and inhalation exposures to diisocyanates. Exposure limits have been established by various regulatory agencies regarding allowable airborne concentrations of diis...

FIRST AID FOLLOWING OVEREXPOSURE Remove individuals affected by overexposure to diisocyanates from the source of exposure. Remove contaminated clothing and place in a plastic bag for decontamination or safe destruction later. Administer first aid immediately....

Adams, W.G., 1975. Long-term effects on the health of men engaged in the manufacture of tolylene di-isocyanate. Brit J Ind Med., 32, 72-78. AGS, 2006. Begründung zu 4-Methyl-m-phenylendiisocyanat in TRGS 900. Ausschuss für Gefahrstoffe, Bundesanstalt für Arbe...